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Determination of Melting Point of Azo Dyes Based on 2,4-dihydroxybenzophenone by Open Capillary Method (CAT#: STEM-PPA-0070-YJL)

Introduction

In the field of azo dyes, phenols and naphthols play major roles for most of the commercial dyes. Most of the dyes are marketed in the form of azo disperse, azo-vat, azo-acid dyes, etc. All have the naphthols moiety bearing hydroxyl group(s) as an auxochrome group. One such compound is 2,4-dihydroxybenzophenone, bearing two hydroxy (as auxochrome) groups and a keto (chromophore) group. This compound has wide applications as a polymer additive. It is an excellent UV absorber, which prevents the photodegradation of most vinyl polymers. Azo dye formation based on this simple compound is an area with has not been developed, except in a few patents. The formation of dyes based on this compound may yield dyes with good hue properties. Hence, it was thought to be of interest to explore the field of azo dyes based on 2,4-dihydroxybenzophenone. In the field of azo dyes, phenols and naphthols play major roles for most of the commercial dyes. Most of the dyes are marketed in the form of azo disperse, azo-vat, azo-acid dyes, etc. All have the naphthols moiety bearing hydroxyl group(s) as an auxochrome group. One such compound is 2,4-dihydroxybenzophenone, bearing two hydroxy (as auxochrome) groups and a keto (chromophore) group. This compound has wide applications as a polymer additive. It is an excellent UV absorber, which prevents the photodegradation of most vinyl polymers. Azo dye formation based on this simple compound is an area with has not been developed, except in a few patents. The formation of dyes based on this compound may yield dyes with good hue properties. Hence, it was thought to be of interest to explore the field of azo dyes based on 2,4-dihydroxybenzophenone.




Principle

Melting point is a characteristic property of solid crystalline substance. It is the temperature at which the solid phase changes to the liquid phase. This phenomenon occurs when the substance is heated.
In all major pharmacopoeias the open capillary method is described to determine the melting point (slip point) for fats, fatty acids, paraffin, and waxes. In a glass capillary tube open at both ends (1), 10 mm of sample is introduced (2), chilled to a given temperature and immersed into a water bath (3/4). The melting point with open capillary, also known as slip point or slip melting point, is the temperature at which the substance begins to rise in the capillary due to the effect of the increasing temperature and buoyancy.

Applications

Chemical industry; Cosmetic/pharmaceutical industry

Procedure

1. Prepare the substance.
2. Affix one of the capillaries to a thermometer.
3. Place the thermometer with an affixed capillary into a glass.
4. Increase the temperature.

Materials

• Sample Type: crystalline compounds