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Study of Melting behavior by Thermomechanical Analysis (TMA) (CAT#: STEM-ACT-0054-WXH)

Introduction

The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa.




Principle

Thermomechanical Analysis (TMA) is a technique in which a deformation of the sample under non-oscillating stress is monitored against time or temperature while the temperature of the sample, in a specified atmosphere, is programmed. The stress may be compression, tension, flexure or torsion.

Applications

It is an excellent tool for studying the expansion behavior and softening temperature of various materials such as thermoplastics, thermosets, elastomers, adhesives and coatings, films and fibers, metals, ceramics and composites.

Procedure

1. Place the specimen on the sample support
2. Place the temperature sensor as close to the specimen as possible
3. Determine the length of the specimen at the beginning of the experiment using a displacement transducer
4. Select the temperature range, rate of rise and fall, and applied load
5. Record the TMA curve as a function of temperature or time
6. Compare the blank curve with the TMA curve obtained from the experiment and perform the required calibration

Materials

• Thermomechanical Analyzers
• Suitable sample matrices: Thermoplastics, Thermosets, Elastomers, Ceramics, Metals, Adhesives