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Study of Broadband Tunable Properties of Surface Plasmon Resonances of Noble Metal Nanoparticles Using Mie Scattering (CAT#: STEM-ST-0084-YJL)

Introduction

Metallic nanoparticles strongly scatter and absorb the incident light due to the excitation of surface plasmons which are the electromagnetic excitation of conduction electrons that exist at metal dielectric interface. The interactions of light to the metal nanoparticles are studied in terms of its resonant peak, which depends on the size, shape and local dielectric environment. Due to sensitive and highly flexible optical properties, noble metal nanoparticles have wide range of applications including biosensing, cancer therapy and photovoltaics, surface-enhanced Raman spectroscopy, optical filters and plasmonic devices.<br />Organic–inorganic-based perovskite photovoltaics are low cost, highly efficient technology to harvest sun light and convert it into the electricity. Recently, perovskite attracted strong interest for the researchers because of its own properties like high absorption coefficient and impressive energy conversion efficiencies. The most widely used perovskite material is methyl ammonium lead triiodide (CH3NH3PbI3) that has a bandgap (EG) of ∼1.57 eV very sharp absorption edge. Perovskites have also one of the promising materials for many applications such as solidstate lighting material lasing applications and have been employed for thin film devices.




Principle

Mie scattering is defined as the type of scattering in which the diameter of the particle is the same or more than the wavelength of the radiation. Mie scattering gives a generalized solution for a system where a scattering of light takes place by a homogenous spherical medium. And this medium should have a refractive index different from that of the medium through which the light is traversing.
Unlike Rayleigh scattering, Mie scattering is not a physically independent phenomenon rather, it is a solution to Maxwell's equations for situations where the phase of the incident angle can change within the dimension of the scattering particles. Mie scattering is more commonly known as Mie solution, and it is named after Gustav Mie, a German physicist.
Mie scattering is also known as aerosol particle scattering, takes place in the atmosphere below 1,500 feet. In Mie scattering, the diameter of the spherical particles through which the light is scattered is approximately equal to the wavelength.

Applications

Mie scattering occurs in a variety of applications, including atmospheric science, cancer detection and treatment, metamaterials, and parasitology. Another application is the characterization of particles by optical scattering measurements.

Procedure

1. Sample preparation
2. Measurement by scattering detection instrument
3. Data analysis

Materials

Mie scattering measurement system