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Determination of total organic carbon in soil solution by conductance technology (CAT#: STEM-PPA-0143-LJX)

Introduction

Soil soluble organic carbon (DOC) refers to all kinds of organic carbon dissolved in soil solution. As an important natural ligand and sorption carrier in the environment,DOC has significant effects on the dissolution, adsorption, desorption, migration and toxicity of chemical substances (such as heavy metals and organic pollutants) in soil through a series of reactions such as adsorption, complexation, chelation and co-precipitation. Therefore, the determination of DOC in soil solution has become an important project in soil chemical property analysis.




Principle

Conductivity method is a commonly used method to measure organic carbon content in water samples. The method is based on the existence of a certain relationship between the electrical conductivity of organic matter and its concentration.
In the process of determination, the water sample to be tested first needs to be pre-treated, such as acidification, filtration, etc., to remove possible interfering substances. The treated water sample is then passed through an conductivity sensor containing a specific membrane to measure the conductivity of the water sample. During the measurement process, the organic matter will interact with the membrane surface, resulting in a decrease in the conductivity of the membrane. By measuring the change of membrane conductivity, the organic carbon content in the water sample can be deduced.

Applications

For the determination of total organic carbon in liquids

Procedure

1. Pre-treat the water sample to be tested
2. Measure the conductivity of the water sample by passing it through a conductivity sensor containing a specific membrane
3. The organic carbon content in the water sample is calculated by measuring the change of membrane conductivity

Materials

• Sample Type:
Soil solution

Notes

In the use of conductance method, due to dissolved oxygen, temperature, salinity and other factors will affect the result. And for some specific organic matter, the conductivity method may have measurement errors. Therefore, real samples need to be verified and calibrated to ensure the accuracy of the measurement results.