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Study of Structural Characterization of Single Carbon Nanotubes by Rayleigh Scattering (CAT#: STEM-ST-0003-YJL)

Introduction

Carbon nanotubes, the prototypical one-dimensional material, are generally chiral except for zigzag and armchair nanotubes. Two nanotube enantiomers, left- and right-handed, can show different interactions with circularly polarized light. From a fundamental point of view, when excited by an external field E, both the electric moment μ and the magnetic moment m exist in chiral nanotubes. Since the orientation of m (determined by the sign of G2) varies with the nanotube handedness, in principle, it is possible to identify the nanotube handedness through circular dichroic spectroscopic techniques.




Principle

The scattering of waves by small impurities (compared to the wavelength) is known as Rayleigh scattering, named after the British physicist who in 1871 first described this phenomenon quantitatively. Rayleigh scattering is a universal mechanism applicable to several contexts, from light scattering (damping of signals in optical fibres) to sound waves in solids and quantum-mechanical wavefunctions of electrons in disordered solids. Mathematically, Rayleigh scattering predicts a mean free path of the wave that varies with wavelength λ, proportional to 1/λ4.

Applications

Rayleigh scattering is used to analyze the properties of the Earth's atmosphere and used in optical communication systems. It is is applicable to scattering of UV and visible radiation by air molecules, infra-red radiation by small aerosols, and microwave radiation by cloud and rain drops.

Procedure

1. Sample preparation
2. Measurement by scattering detection instrument
3. Data analysis

Materials

Rayleigh scattering measurement system