In materials science, stress relaxation is the observed decrease in stress in response to strain generated in the structure. This is primarily due to keeping the structure in a strained condition for some finite interval of time hence causing some amount of plastic strain.
The main structural relaxation in polymers is the segmental, so-called α-relaxation. It controls diffusion and viscosity, rotation of monomers. The α-process is the relaxation on time scale shorter than the rubbery plateau and the Rouse modes.