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Trace elemental analyses by spark source mass spectrometry (CAT#: STEM-ST-0276-LJX)

Introduction

Spark source mass spectrometry provides unique capabilities in trace elemental analyses which have been useful in the examination of materials of forensic interest. Response of this technique to all inorganic elements, sensitivities to the ppb range, and qualitative-quantitative data display allow acquisition of trace element "profiles" for comparison and identification purposes. Sample preparation and pretreatment is quite important. Instrumental parameters must also be carefully controlled, including spark conditions, electrode position, and ion flux. Materials studied in our laboratories include metallurgicals, synthetic fibers, and graphites as well as human hair, blood, nails, and tissues.




Principle

By using vacuum spark discharge, the energy accumulated in a small volume can make the material in the volume suddenly evaporate and ionize, so as to obtain the characteristic ion current information.

Applications

(1) Solid spark source mass spectrometry: impurity analysis of high-purity materials, which can be applied to semiconductor materials, non-ferrous metals, and building materials industries;
(2) Gas isotope mass spectrometry: determination of stable isotopes C, H, N, O, S and radioactive isotopes Rb, Sr, U, Pb, K, Ar, which can be applied to geology, petroleum, medicine, environmental protection and agriculture.

Procedure

(1) An electric field is applied between the electrodes to ionize part of the carrier gas (such as argon) in the electric field;
(2) The "cathode ray" or "anode ray" generated by ionization accelerates in the direction of the opposite polarity in the residual gas, bombards the anode or cathode, and vaporizes a part of the substance to be measured on the plate;
(3) Part of the atoms of the vaporized substance are ionized in the subsequent discharge process.

Materials

• Sample Type:
Trace element

Notes

Before starting the machine, check whether the water (water cooler), electricity, gas (argon/nitrogen), temperature, humidity, and exhaust air of the instrument are normal.