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Magnetic transition in compressed Fe3C by X-Ray Emission Spectroscopy (XES) (CAT#: STEM-ST-0285-WXH)

Introduction

Cementite (or iron carbide) is a compound of iron and carbon, more precisely an intermediate transition metal carbide with the formula Fe3C. By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. It is a hard, brittle material, normally classified as a ceramic in its pure form, and is a frequently found and important constituent in ferrous metallurgy. While cementite is present in most steels and cast irons, it is produced as a raw material in the iron carbide process, which belongs to the family of alternative ironmaking technologies.




Principle

XES is an element-specific method primarily used to analyze the partially occupied electronic structure of materials. The technique is one of the photon-in-photon-out spectroscopies in which an incident X-ray photon is used to excite a core electron, which leads to the transition of the electron from the ground state to the excited state, and then the excited state of the electron decays with the emission of an X-ray photon in order to fill the core hole.

Applications

Used for the study of electronic structure and for the qualitative and quantitative analysis of substances.

Materials

• X-ray emission spectrometer
• X-ray generating equipment (X-ray tube)
• Collimators
• Monochromators
• X-ray detectors