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Analysis of III—V semiconductors by spark-source mass spectrometry (CAT#: STEM-ST-0273-LJX)

Introduction

The service analyzed the III—V semiconducting materials by sparksource mass spectrometry, which is especially suitable for the characterization of indium phosphide single crystals. As a means of standardization, some of the crystals were doped either uniformly during growth or by implantation of a well-defined dopant at levels of 1014–1015 atoms cm-2. Implantation is shown to be valuable for providing standards at low levels of impurities. The main impurities in indium phosphide single crystals are Si, C, O, B, N, Al, (S), Zn and As, but sixteen other elements are present below the detection limit. In a single crystal grown by the liquid encapsulation technique, two types of impurity segregation, along the axis of growth and along the radial axis, are revealed.




Principle

By using vacuum spark discharge, the energy accumulated in a small volume can make the material in the volume suddenly evaporate and ionize, so as to obtain the characteristic ion current information.

Applications

(1) Solid spark source mass spectrometry: impurity analysis of high-purity materials, which can be applied to semiconductor materials, non-ferrous metals, and building materials industries;
(2) Gas isotope mass spectrometry: determination of stable isotopes C, H, N, O, S and radioactive isotopes Rb, Sr, U, Pb, K, Ar, which can be applied to geology, petroleum, medicine, environmental protection and agriculture.

Procedure

(1) An electric field is applied between the electrodes to ionize part of the carrier gas (such as argon) in the electric field;
(2) The "cathode ray" or "anode ray" generated by ionization accelerates in the direction of the opposite polarity in the residual gas, bombards the anode or cathode, and vaporizes a part of the substance to be measured on the plate;
(3) Part of the atoms of the vaporized substance are ionized in the subsequent discharge process.

Materials

• Sample Type:
III—V semiconductors

Notes

Before starting the machine, check whether the water (water cooler), electricity, gas (argon/nitrogen), temperature, humidity, and exhaust air of the instrument are normal.